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Highly Stereoselective Synthesis of 1,6-Ketoesters Mediated by Ionic Liquids: A Three-component Reaction Enabling Rapid Access to a New Class of Low Molecular Weight Gelators
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Highly Stereoselective Synthesis of 1,6-Ketoesters Mediated by Ionic Liquids: A Three-component Reaction Enabling Rapid Access to a New Class of Low Molecular Weight Gelators

Highly Stereoselective Synthesis of 1,6-Ketoesters Mediated by Ionic Liquids: A Three-component Reaction Enabling Rapid Access to a New Class of Low Molecular Weight Gelators

DOI:
10.3791/53213-v

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06:31 min

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November 27, 2015

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, ,
1Chemistry and Chemical Engineering,Chalmers University of Technology

Chapitres

  • 00:05Titre
  • 01:14Gram-scale Synthesis of Methyl 6-oxo-3,4,6-triphenylhexanoate
  • 03:34Recycling of EMIMAc and Gelation
  • 04:36Results: Analysis of Three-component Synthesis of 1,6-Ketoester
  • 05:35Conclusion

Summary

Traduction automatique

Traduction automatique

Ionic liquids (ILs) mediate fast, simple and cheap access to 1,6-ketoesters in high diastereoselectivities and good yields. The reaction protocol is robust and the 1,6-ketoesters can be obtained in gram scale after a simple filtration protocol. Moreover, the 1,6-ketoesters are potent gelators in hydrocarbon solvents.

Tags

Keywords: Ionic LiquidsN-Heterocyclic Carbenes16-ketoestersStereoselective SynthesisChalconesAldehydesLow Molecular Weight Gelators (LMWGs)RecyclableScalableFunctional Group Tolerance

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