Rivista
/
Chimica
/
Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework
JoVE Journal
Chimica
È necessario avere un abbonamento a JoVE per visualizzare questo.  Accedi o inizia la tua prova gratuita.
JoVE Journal Chimica
Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework

Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework

DOI:
10.3791/57455-v

•

12:30 min

•

April 09, 2018

•

, , ,
1School of Chemical Engineering and Light Industry,Guangdong University of Technology, 2Department of Chemistry,City University of Hong Kong

Capitoli

  • 00:04Titolo
  • 00:49Sodium Thiomethoxide (CH3SNa) Synthesis
  • 03:092,3,6,7,10,11-Hexakis(pentanoylthio)triphenylene (HVaTT) Synthesis
  • 07:45Lead 2,3,6,7,10,11-Triphenylene Hexathiol (HTT-Pb) Framework Single Crystal Synthesis and Interaction with Paraquat Diiodide
  • 10:13Results: HVaTT and HTT-Pb ([Pb3OH0.5(HTT)]-1.5) Characterization
  • 11:47Conclusion

Summary

Traduzione automatica

Traduzione automatica

Here, we present a one-pot, transition-metal-free synthesis of thiols and thioesters from aromatic halides and sodium thiomethoxide, followed by the preparation of single crystals of a metal-dithiolene network using thiol species generated in situ from the more stable and tractable thioester.

Tags

Thiol LinkerMetal-sulfur FrameworkCrystallizationSemiconducting GyroidalThioesterMercaptanMetal IonsSodium ThiomethoxideHVaTT Synthesis

Article

Embed

AGGIUNGI ALLA PLAYLIST

Usage Statistics

Video correlati

Preparation and Use of Samarium Diiodide (SmI2) in Organic Synthesis: The Mechanistic Role of HMPA and Ni(II) Salts in the Samarium Barbier Reaction

Synthesis and Purification of Iodoaziridines Involving Quantitative Selection of the Optimal Stationary Phase for Chromatography

Synthesis and Exfoliation of Discotic Zirconium Phosphates to Obtain Colloidal Liquid Crystals

Synthesis of Programmable Main-chain Liquid-crystalline Elastomers Using a Two-stage Thiol-acrylate Reaction

Synthesis of Cd-free InP/ZnS Quantum Dots Suitable for Biomedical Applications

HKUST-1 as a Heterogeneous Catalyst for the Synthesis of Vanillin

Sulfate Separation by Selective Crystallization with a Bis-iminoguanidinium Ligand

Synthesis of a Water-soluble Metal–Organic Complex Array

Electrophoretic Crystallization of Ultrathin High-performance Metal-organic Framework Membranes

Solid-phase Synthesis of [4.4] Spirocyclic Oximes

Read Article