Triazole and Tetrazole Functionalized Zr-MOFs Synthesis and Characterization

June 23, 2023

Functionalizing Metal-Organic Frameworks: Advancements, Challenges, and the Power of Post-Synthetic Ligand Exchange (Video) | JoVE

01:34 min

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Setting up the Post-synthetic Ligand Exchange (PSE) Process, Exchanged MOF Isolation and Washing Process (Video) | JoVE

01:28 min

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Characterization of the MOF by Powder X-Ray Diffraction (PXRD) and Nuclear Magnetic Resonance (NMR) After Digestion (Video) | JoVE

02:09 min

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Sangho Lee*¹, Daeyeon Lee*¹, Jin Yeong Kim, Min Kim

¹Department of Chemistry,Chungbuk National University, ²Department of Chemistry Education,Seoul National University

Summary

Post-synthetic ligand exchange (PSE) is a versatile and powerful tool for installing functional groups into metal-organic frameworks (MOFs). Exposing MOFs to solutions containing triazole- and tetrazole-functionalized ligands can incorporate these heterocyclic moieties into Zr-MOFs through PSE processes.

Triazole and Tetrazole Functionalized Zr-MOFs Synthesis and Characterization

Functionalizing Metal-Organic Frameworks: Advancements, Challenges, and the Power of Post-Synthetic Ligand Exchange (Video) | JoVE

Setting up the Post-synthetic Ligand Exchange (PSE) Process, Exchanged MOF Isolation and Washing Process (Video) | JoVE

Characterization of the MOF by Powder X-Ray Diffraction (PXRD) and Nuclear Magnetic Resonance (NMR) After Digestion (Video) | JoVE

Summary

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