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Chapters
- 00:00Title
- 03:46Synthesis of Phenyl HIAT
- 05:35Synthesis of n-Pentyl HIAT
- 08:33O-H insertion cyanocarbene reaction using Phenyl HIAT
- 10:17Cylcopropanation cyanocarbene reaction using Phenyl HIAT
- 11:50Conclusion
Herein is described the synthesis, isolation, and reactions of hypervalent iodonium alkynyl triflates (HIATs) with azides to generate cyanocarbenes. The procedures will involve air-sensitive and cryogen techniques, including cold filtration under an inert atmosphere. Handling and safety of the synthesized compounds will also be discussed.
