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Chapter 18

Chapter 18

Electrochemistry

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Electrochemistry is the science involved in the interconversion of electrical and chemical reactions. Such reactions are called reduction-oxidation, or …
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Electricity is generated by either electrons or ions flowing through a solution or a conducting medium. This flow of electrons or specifically electrical …
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Spontaneous Chemical Reactions Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering …
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On comparing the reactivity of silver and lead, it is observed that the two ionic species, Ag+ (aq) and Pb2+ (aq), show a difference in their redox …
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Thermodynamics of a Redox Reaction Thermodynamics is the branch of physics dealing with the relationship between heat and other forms of energy. In an …
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Nonstandard Reaction Conditions The interconnection between standard cell potentials and various thermodynamic parameters such as the standard free energy …
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A concentration cell is a type of a  voltaic cell constructed by connecting two almost identical half-cells, both based on the same half-reaction and …
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A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to …
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The degradation of metals due to natural electrochemical processes is known as corrosion. Rust formation on iron, tarnishing of silver, and the blue-green …
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In a galvanic cell, the electrical work is done by a redox system on its surroundings as electrons produced by the spontaneous redox reactions are …
Here we demonstrate the method of electrochemical gating used to characterize electrical conductivity of electrode-grown microbial biofilms under …
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A novel electrochemical cell based on a CaF2 solid-state electrolyte has been developed to measure the electromotive force (emf) of binary alkaline …
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Material corrosion can be a limiting factor for different materials in many applications. Thus, it is necessary to better understand corrosion processes, …