프로필렌 글리콜 용액의 점도
English
COMPARTILHAR
Visão Geral
출처: 마이클 G. 벤턴과 케리 M. 둘리,화학 공학부, 루이지애나 주립 대학, 배턴 루지, LA
점도는 유체의 흐름 저항을 측정한 것이며, 광범위한 산업에서 효율적인 제품 처리 및 품질 관리 설계에 유용한 파라미터입니다. 다양한 점도계가 실험 물질의 가장 정확한 판독값을 얻기 위해 사용됩니다. 점도를 측정하는 표준 방법은 유리 튜브 점성을 통해 유리튜브 1로만들어진 모세관 튜브를 통해 유체가 흐르는 데 걸리는 시간을 측정하여 점도를 추정합니다.
회전 점도는 전단력을 적용하고 흐르는1을걸리는 시간을 측정하여 작동합니다. 이러한 점도계는 유체의 흐르는 힘을 사용하며 스프링 시스템 또는 디지털 인코더 시스템1을사용할 수 있습니다. 표준이 원뿔 모양 아래 플레이트 위로 흐르는 원뿔 및 플레이트 시스템인 표준과 함께 전단 응력1을최소화하기 위해 다양한 측정 시스템이 존재한다. 병렬 플레이트 시스템은 두 개의 병렬 플레이트를 사용하며 온도 그라데이션 을 가로질러 측정하는 데 적합하므로 원활한 전환1을허용합니다. 쿠엣 시스템은 컵과 충전재를 사용하고, 유체는 두1사이에 흐른다. 이 시스템은 전단 응력 최소화를 최소화하기 때문에 점도가 낮은 재료에 가장 적합하지만, 시스템은 또한 더 많은 양의 유체1을세척하고 필요로 하는 문제로 인해 일상적으로 작동하기가 더 어렵습니다.
이 실험에서, 캐논-펜스케 점도는 점도와 조성물의 관계를 결정하기 위해 여러 프로필렌 글리콜 솔루션의 점도를 측정하는 데 사용될 것이다.
Princípios
Procedimento
Resultados
In this experiment, the viscosity of several concentrations of propylene glycol were measured. As expected, the viscosity was found to increase with propylene glycol concentration. The time for the sample solutions to traverse the viscometer were measured and used to determine the kinematic viscosity. Numerous measurements were collected to minimize random error.
The kinematic viscosity was determined using the time as measured and the viscometer constant:
Then, the kinematic viscosity was multiplied by the density to give the dynamic viscosity:
The unknown concentration was calculated and compared to the known sample solutions. Linear interpolation was used to estimate the concentration, and the relationship was best fit to a linear function (Figure 1).
For the above equation, two known data points of kinematic viscosity and concentration were used, and x was set as the measured viscosity of the unknown solution. The solution was solved for y to find the concentration of the unknown sample. The Excel graphing feature can also be used to plot a trendline through the data set and give an equation of best fit.
Figure 1: The relationship between concentration of solution and viscosity demonstrated a linear fit.
This graph shows that the natural logarithm of viscosity and composition follow a linear relationship. As solute composition increases in a solution, viscosity also increases. Knowing this relationship, the concentration of the unknown solution is easily found by measuring its viscosity and relating it to the known relationship between concentration and viscosity. The experimental accuracy can be improved by measuring more known concentrations or using a more precise thermometer.
Applications and Summary
The goal of this experiment was to test the relationship of viscosity and composition by using the viscosity of the unknown substance to find its composition. A number of known concentration solutions of propylene glycol and one unknown concentration solution were tested. Relationships between density, dynamic viscosity, and kinematic viscosity were used to compare the solutions. Since solutions become more viscous as they became more concentrated, we were able to narrow the concentration of the unknown solution to a small range. Linear interpolation was used to estimate the concentration, and the relationship was best fit to a linear function. For this experiment, increasing the accuracy of the thermometer could have decreased our uncertainty significantly, since it is the main source of error. More concentrations could also have been tested to increase the precision.
Accurate viscosity testing is important to a variety of fields. In the food processing industry, food must be tested for viscosity throughout its creation as it is transported throughout a facility2. These measurements are used to maximize the efficiency of the process and to establish standards for production2. The viscosity is important to the food industry because it will determine how long transport of food through a pipe or processor will take, how long it will take food to dry, and the time it will take to dispense food into packaging for transportation and retail2. Engineers will use the viscosity to maximize flow of the product through piping in order to save energy and maximize the product, without diminishing the quality of the finished product2. Viscosity is also important to establish safe standards for the force that can be applied to materials and product without damaging it2.
In the petroleum industry, viscosity is an important control for quality assessment3. When purchasing or processing crude oil, companies must measure the viscosity to determine the appropriate treatment3. The viscosity provides important information about the composition of the crude oil3. Oil of different compositions is used to create different products3. Some refineries can only process oils of a certain viscosity, so accurate testing is important to determine which materials they can use for refining3. In oil refining, the viscosity of the oil is used to plan the most efficient methods for extraction, transportation, and refining method3. Temperature can also have an impact on the viscosity of oil, so controls must be put in place to have the oil at an appropriate temperature for its viscosity3. Additionally, the viscosity of an oil will determine the way it is cleaned up in the case of a leak3.
Referências
- Basic Introduction to Viscometry." A Basic Introduction to Viscometry. N.p., n.d. Web. 7 Jan. 2017.
- Scientific. "What is Viscosity, and Why is Measuring Viscosity Important?" What is Viscosity, and Why is Measuring Viscosity Important? N.p., n.d. Web. 7 Jan. 2017.
- Applications." Anton Paar. N.p., n.d. Web. 13 Jan. 2017.
Transcrição
Viscosity is a measure of a fluid’s resistance to flow and it is a useful parameter in the design of efficient product processing and quality control in a wide range of industries. Viscosity describes the internal friction of a moving fluid. A fluid with a high viscosity resists flow, whereas a fluid with a low viscosity flows more easily. A glass tube viscometer is commonly used to determine viscosity, which measures the time it takes for a fluid to flow through a capillary tube. Rotational viscometers such as with a parallel plate geometry, apply shearing forces and measure the torque required to rotate the fluid. This video illustrates the principles of viscosity, demonstrates how to use a viscometer to determine the unknown concentration of a propylene glycol solution, and discusses some industrial applications.
To begin, let’s review the principles of viscosity. The dynamic viscosity of a fluid describes the force per unit surface area, known as the shear stress, that is required to move fluid, in this case, parallel to a plane. The fluid in close contact with the bottom plate stays at rest, and the fluid touching the top plate is the same speed as that plate. This velocity gradient is due to internal friction between layers of fluid, and is known as the rate of shear deformation. The dynamic viscosity is defined as the shear stress divided by the rate of shear deformation. The viscosity can be influenced by temperature, fluid density, and composition. Pressure changes, however, have a negligible effect. Once the dynamic viscosity is known, the kinematic viscosity is the ratio of dynamic viscosity to the fluid’s density. This is a measure of the fluid’s resistance to flow due to gravity. Several instruments measure kinematic viscosity experimentally, such as the Canon-Fenske viscometer. This apparatus consists of a large temperature controlled water bath with fins to maintain constant thermo equilibrium. Different sized capillary tubes are used depending on the approximate fluid’s viscosity. Using this apparatus, fluid is poured into the tube and suctioned past the etched markings. Then, the time required for the fluid to travel back through the capillary tube is measured, known as the efflux time. The efflux time is then multiplied by the viscometer calibration constant, which is specific to the capillary glass used to give the kinematic viscosity. Now that you know the fundamentals of viscosity, let’s measure the kinematic viscosity of known propylene glycol solutions to determine the concentration of an unknown sample.
Start the experiment by preparing seven solutions for calibration with varying concentrations of propylene glycol and water. Label all solutions with the concentration. Obtain a sample of the unknown concentration, and set it aside. Check all liquid samples for lint, dust, or solid particles before using, and if necessary, filter the sample through a centered glass filter. Next, clean the viscometer using water and dry it with filtered air. Remember to use the appropriate size glass capillary tube for the viscometer, which is dependent on the approximate viscosity of the solution to be tested.
Now, pour a sample into the viscometer, then wipe the arm clean. Next, place the viscometer into the holder and insert it into the temperature bath. Wait 10 to 15 minutes to allow the sample to equilibrate to the bath temperature. Then apply suction to the arm, and draw the sample into the tube. Now take a stopwatch and measure the time required for the sample to flow freely down the capillary tube after leaving the marked end point. This is your efflux time. Repeat the procedure for each sample. Now that all of the viscosities have been measured, let’s take a look at the results and determine the concentration of the unknown sample.
To find the concentration of the unknown sample use the data of the known samples and interpolate the viscosity of the unknown solution. First, determine the kinematic viscosities by multiplying the measured time by the viscometer constant. Then convert the kinematic viscosity to dynamic viscosity by multiplying by the mass density. Next, plot the kinematic viscosities as a function of the molarities of the known samples. The graph shows that viscosity increases with increasing propylene glycol concentration. Determine the linear relationship between kinematic viscosity and propylene concentration. Then, interpolate the concentration of the unknown sample using its measured viscosity. In this demonstration, the unknown sample contained 45 mol percent of propylene glycol. Now that you have learned how the viscosity is used to determine concentration, let’s examine the many applications of viscosity in industrial settings.
Testing viscosity is important in many industrial fields ranging from petroleum refinery and solar cell production to biomedical applications and research. The precise measurement of viscosity in the petrochemical industry is of high priority because it is used not only to determine crude oil composition, but also to evaluate quality control in petrochemical products. Viscosity varies from crude oil to liquid hydrocarbons, and it must be considered for efficient extraction, handling, and refinery operational conditions. Rheological characterization of highly concentrated suspensions is also mandatory for product development of applications involving complex fluids, such as those used in the metalization of solar cells. The flow properties of conductive pastes have to be carefully adjusted to guarantee undisturbed, defect-free processing and prevent sedimentation and particle aggregation. In medicine, micro rheological techniques are diagnostic tools that investigate red blood cell deformability, and detect blood diseases such as sickle cell anemia, which affect blood viscosity. Protocols utilizing micro fluidics with adjustable shear rates and image processing are utilized to quantitatively determine red blood cell aggregation in microcirculation. These protocols are also used to characterize human tissue, such as brain matter, to better understand structure and engineer bio inspired materials.
You’ve just watched JOVE’s introduction to viscosity. You should now know the fundamental principles of viscosity, be able to operate a viscometer, and understand the importance of viscosity in a variety of applications. Thanks for watching.