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基于末端碘氧化炔烃的 1-Iodoalkynes、12-Diiodoalkenes、11、2 Triiodoalkenes 的 Chemoselective 制备
JoVE Journal
Química
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JoVE Journal Química
Chemoselective Preparation of 1-Iodoalkynes, 1,2-Diiodoalkenes, and 1,1,2-Triiodoalkenes Based on the Oxidative Iodination of Terminal Alkynes
DOI:

09:54 min

September 12, 2018

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Capítulos

  • 00:04Título
  • 01:15Synthesis of 1-(Iodoethynyl)-4-Methylbenzene (Compound 2)
  • 03:16Synthesis of (E)-1-(1,2-Diiodovinyl)-4-Methylbenzene (Compound 3)
  • 04:44Synthesis of 1-Methyl-4-(1,2,2-Triiodovinyl)benzene (Compound 4)
  • 06:58Determination of Selectivity for Mono-, Di-, or Tri-Iodination of Terminal Alkynes by HPLC
  • 07:53Results: Chemoselective Synthesis of 1-Iodoalkynes, 1,2-Diiodoalkenes, and 1,1,2-Triiodoalkenes
  • 09:37Conclusion

Summary

Tadução automática

本文介绍了用高价碘试剂对炔烃末氧化碘的详细协议, chemoselectively 提供了 1 iodoalkynes、12 diiodoalkenes、11、2 triiodoalkenes。

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