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功能化单有机硼化合物共轭法高效合成全碳第四纪中心

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Química

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JoVE Journal Química

Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides

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功能化单有机硼化合物共轭法高效合成全碳第四纪中心

DOI:

10.3791/59775-v

•

07:50 min

•

May 26, 2019

•

Tyler J. Fulton, Katherine M. Townsend, Michael R. Krout

¹Warren and Katharine Schlinger Laboratory for Chemistry and Chemical Engineering,California Institute of Technology, ²Department of Chemistry,Bucknell University

Capítulos

00:04Título
00:32Functionalized Monoorganozinc Bromide Formation and Monoorganozinc Bromide Conjugate Addition to α,β-Unsaturated Ketones
02:26Extraction Work-up and Purification
05:44Results: Data Analysis and Reaction Scope
07:19Conclusion

Summary

Tadução automática

提出了一种将功能化的单有机酶溴有效地结合在环α、β-不饱和碳基中的全碳第四纪中心的简单实用的协议。

Tags

Keywords: Copper-mediated Conjugate Addition Monoorganozinc Bromides Cyclic Alpha-beta-unsaturated Carbonyls Quaternary Centers Dimethylacetamide Organobromides Organozinc Formation Silyl Enol Ether Hydrolysis

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