Andreas Schnepf Chemistry Department, Institute of Inorganic Chemistry University of Tübingen Biography Publications Institution JoVE Articles Andreas Schnepf has not added a biography. If you are Andreas Schnepf and would like to personalize this page please email our Author Liaison for assistance. Publications Reactivity of [Ge9{Si(SiMe3)3}3]- Towards Transition Metal M2+ Cations : Coordination and Redox Chemistry Chemistry (Weinheim an Der Bergstrasse, Germany). Oct, 2016 | Pubmed ID: 27796057 IPr3 Si3 Cl5 (+) : A Highly Reactive Cation with Silanide Character Chemistry (Weinheim an Der Bergstrasse, Germany). Jul, 2016 | Pubmed ID: 27258331 The Largest Metalloid Group 14 Cluster, Ge18[Si(SiMe3)3]6 : An Intermediate on the Way to Elemental Germanium Angewandte Chemie (International Ed. in English). Feb, 2016 | Pubmed ID: 26822765 {Ge9[Si(SiMe3)2(SiPh3)]3}(-): Ligand Modification in Metalloid Germanium Cluster Chemistry Inorganic Chemistry. Jul, 2015 | Pubmed ID: 26154728 Reactions with a Metalloid Tin Cluster {Sn10[Si(SiMe3)3]4}(2-): Ligand Elimination Versus Coordination Chemistry Chemistry (Weinheim an Der Bergstrasse, Germany). Jun, 2015 | Pubmed ID: 26095993 Reactions with a Metalloid Tin Cluster {Sn10[Si(SiMe3)3]4}(2-): Ligand Elimination Versus Coordination Chemistry Chemistry (Weinheim an Der Bergstrasse, Germany). May, 2015 | Pubmed ID: 25892180 {Sn10 [Si(SiMe3 )3 ]4 }(2-) : A Highly Reactive Metalloid Tin Cluster with an Open Ligand Shell Chemistry (Weinheim an Der Bergstrasse, Germany). Feb, 2015 | Pubmed ID: 25430476 Dative or Not Dative? Angewandte Chemie (International Ed. in English). Jun, 2014 | Pubmed ID: 24889370 Nanoscale Molecular Silver Cluster Compounds in Gram Quantities Angewandte Chemie (International Ed. in English). Mar, 2014 | Pubmed ID: 24519816 Dative Bonds in Main-group Compounds: a Case for Fewer Arrows! Angewandte Chemie (International Ed. in English). Jan, 2014 | Pubmed ID: 24243854 [Ge12{FeCp(CO)2}8{FeCp(CO)}2]: a Ge12 Core Resembles the Arrangement of the High-pressure Modification Germanium (II) Angewandte Chemie (International Ed. in English). Feb, 2013 | Pubmed ID: 23288682 {Sn9[Si(SiMe3)3]2}2-: a Metalloid Tin Cluster Compound with a Sn9 Core of Oxidation State Zero Inorganic Chemistry. Aug, 2012 | Pubmed ID: 22804582 {Sn9[Si(SiMe3)3]3}− and {Sn8Si[Si(SiMe3)3]3}−: Variations of the E9 Cage of Metalloid Group 14 Clusters Inorganic Chemistry. Apr, 2012 | Pubmed ID: 22436071 [Sn4Si{Si(SiMe3)3}4{SiMe3}2]: a Model Compound for the Unexpected First-order Transition from a Singlet Biradicaloid to a Classical Bonded Molecule Angewandte Chemie (International Ed. in English). Aug, 2011 | Pubmed ID: 21698735 [Si(SiMe3)3]3Ge9M(CO)3(-) (M=Cr, Mo, W): Coordination Chemistry with Metalloid Clusters Dalton Transactions (Cambridge, England : 2003). Jul, 2011 | Pubmed ID: 21614350 The Formal Combination of Three Singlet Biradicaloid Entities to a Singlet Hexaradicaloid Metalloid Ge14[Si(SiMe3)3]5[Li(THF)2]3 Cluster Journal of the American Chemical Society. Mar, 2011 | Pubmed ID: 21302926 Sn[Si(SiMe3)3]3- and Sn3[Si(SiMe3)3]4: First Insight into the Mechanism of the Disproportionation of a Tin Monohalide Gives Access to the Shortest Double Bond of Tin Chemical Communications (Cambridge, England). Sep, 2010 | Pubmed ID: 20717582 The Formation of a Metalloid Sn(10)[Si(SiMe(3))(3)](6) Cluster Compound and Its Relation to the Alpha<-->beta Tin Phase Transition Dalton Transactions (Cambridge, England : 2003). Feb, 2010 | Pubmed ID: 20449434 [Si(SiMe3)3]6Ge18M (M = Zn, Cd, Hg): Neutral Metalloid Cluster Compounds of Germanium As Highly Soluble Building Blocks for Supramolecular Chemistry Dalton Transactions (Cambridge, England : 2003). Nov, 2009 | Pubmed ID: 20449189 {Ge9R3Cr(CO)5}- and {Ge9R3Cr(CO)3}-: a Metalloid Cluster (Ge9R3-) As a Flexible Ligand in Coordination Chemistry [R=Si(SiMe3)3] Chemical Communications (Cambridge, England). Jun, 2009 | Pubmed ID: 19587915 [(OtBu)(2)C(6)H(3)](3)Ge(+) a Free Germyl Cation with Aryl Ligands Dalton Transactions (Cambridge, England : 2003). Feb, 2009 | Pubmed ID: 19156269 Ge(14)[Ge(SiMe(3))(3)](5)Li(3)(THF)(6): the Largest Metalloid Cluster Compound of Germanium: on the Way to Fullerene-like Compounds? Chemical Communications (Cambridge, England). Oct, 2008 | Pubmed ID: 18815711 Si@Al56[N(2,6-iPr2C6H3)SiMe3]12: the Largest Neutral Metalloid Aluminum Cluster, a Molecular Model for a Silicon-poor Aluminum-silicon Alloy? Angewandte Chemie (International Ed. in English). 2008 | Pubmed ID: 18814152 [Si(SiMe(3))(3)](6)Ge(18)M (M = Cu, Ag, Au): Metalloid Cluster Compounds As Unusual Building Blocks for a Supramolecular Chemistry Dalton Transactions (Cambridge, England : 2003). Sep, 2008 | Pubmed ID: 18698446 Ge4Br4[Mn(CO)5]4 and Ge6Br2[Mn(CO)5]6: First Germanium Cluster Compounds Containing Mn(CO)5 Ligands Dalton Transactions (Cambridge, England : 2003). Dec, 2007 | Pubmed ID: 18026588 [AuGe18{Si(SiMe3)3}6]-: a Soluble Au-Ge Cluster on the Way to a Molecular Cable? Angewandte Chemie (International Ed. in English). 2007 | Pubmed ID: 17579905 Metalloid Group 14 Cluster Compounds: an Introduction and Perspectives to This Novel Group of Cluster Compounds Chemical Society Reviews. May, 2007 | Pubmed ID: 17471399 {Ge10Si[Si(SiMe3)3]4(SiMe32)Me}-: a Ge10Si Framework Reveals a Structural Transition Onto Elemental Germanium Chemical Communications (Cambridge, England). Jan, 2007 | Pubmed ID: 17180243 Na6[Ge10{Fe(CO)4}8]18 THF: a Centaur Polyhedron of Germanium Atoms Angewandte Chemie (International Ed. in English). Aug, 2006 | Pubmed ID: 16847861 Ge8R6: the Ligands Define the Bonding Situation Within the Cluster Core Dalton Transactions (Cambridge, England : 2003). Oct, 2005 | Pubmed ID: 16193145 Subvalent Compounds Featuring Direct Metal-metal Bonds: the Zn-Zn Bond in [Cp*2Zn2] Angewandte Chemie (International Ed. in English). May, 2005 | Pubmed ID: 15844126 Two Metalloid Ga22 Clusters Containing a Novel Ga22 Core with an Icosahedral Ga12 Center Chemistry (Weinheim an Der Bergstrasse, Germany). Apr, 2004 | Pubmed ID: 15079837 Novel Compounds of Elements of Group 14: Ligand-stabilized Clusters with "naked" Atoms Angewandte Chemie (International Ed. in English). Jan, 2004 | Pubmed ID: 14755694 Preparation and Precise Structural Determination of a Second Ga84 Cluster Compound. A First Hint for Cluster Doping and Its Fundamental Consequences in the Field of Chemistry and Physics of Nanoscaled Metalloid Cluster Material Inorganic Chemistry. Dec, 2003 | Pubmed ID: 14632487 [Ge9[Si(SiMe3)3]3]-: a Soluble Polyhedral Ge9 Cluster Stabilized by Only Three Silyl Ligands Angewandte Chemie (International Ed. in English). Jun, 2003 | Pubmed ID: 12813736 [Ge8[N(SiMe3)2]6]: a Ligand-stabilized Ge Cluster Compound with Formally Zero-valent Ge Atoms Angewandte Chemie (International Ed. in English). Feb, 2003 | Pubmed ID: 12596175 [Ga22{N(SiMe3)2}10]2-: a Metalloid Cluster Compound with a Variation of the Ga22 Framework Angewandte Chemie (International Ed. in English). Jun, 2002 | Pubmed ID: 19750621 Metalloid Aluminum and Gallium Clusters: Element Modifications on the Molecular Scale? Angewandte Chemie (International Ed. in English). Oct, 2002 | Pubmed ID: 12370894 A Ga(8)R(6) Cluster As an Ideal Model for a Metal-Metal Bond? This Work Was Supported by the Deutsche Forschungsgemeinschaft and by the Fonds Der Chemischen Industrie Angewandte Chemie (International Ed. in English). Apr, 2001 | Pubmed ID: 11301437 Synthesis and Structure of a Ga(84)R(20)(4-) Cluster-A Link Between Metalloid Clusters and Fullerenes? This Work, Which Had Originally Been Submitted to Nature in September 1999 and Has Been Presented in Part in Lectures Since January 2000, Was Supported by the Deutsche Forschungsgemeinschaft and the Fonds Der Chemischen Industrie Angewandte Chemie (International Ed. in English). Feb, 2001 | Pubmed ID: 11241599 A síntese de [Sn Mareike Binder1, Claudio Schrenk1, Andreas Schnepf1 1Chemistry Department, Institute of Inorganic Chemistry, University of Tübingen Chemistry
A síntese de [Sn Mareike Binder1, Claudio Schrenk1, Andreas Schnepf1 1Chemistry Department, Institute of Inorganic Chemistry, University of Tübingen Chemistry