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Combining Solid-state and Solution-based Techniques
 

Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of Chalcogenidoplumbates(II or IV)

Article DOI: 10.3791/54789-v • 10:42 min • December 29th, 2016
December 29th, 2016 •
1, 2, 2, 2
1Department of Chemistry, University of California, Berkeley, 2Fachbereich Chemie, Philipps-Universität Marburg and Wissenschaftliches Zentrum für Materialwissenschaften

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Resumen
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The synthesis of chalcogenidoplumbates(II,IV) via the in situ reduction of nominal "PbCh2" (Ch = Chalcogen) and via a solid-state reaction and subsequent solvothermal reactions is presented. Additionally, reactivities of plumbate(II) solutions are portrayed, which yield the heaviest-known CO homolog known to date: the µ-PbSe ligand.

Tags

Solid-state Solution-based Synthesis Reactivity Chalcogenidoplumbates Semi-conducting Properties Inorganic Chemistry Materials Chemistry Traditional Synthetic Methods Oxidation States Coordination Modes Ligands High-yielding Pure Metallate Iron Solutions Precursors Reactivity Studies Metalloid Compounds Heaviest Metal Atoms Metallates Air Exclusion Moisture Exclusion Light Exclusion Dry Solvents Diaminoethane Calcium Hydride Tetrahydrofuran (THF) Sodium-potassium Alloy
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