Pierangelo Metrangolo Laboratory of Supramolecular and Bio-Nanomaterials (SBNLab), Department of Chemistry, Materials, and Chemical Engineering "Giulio Natta" Politecnico di Milano Biography Publications Institution JoVE Articles Pierangelo Metrangolo has not added a biography. If you are Pierangelo Metrangolo and would like to personalize this page please email our Author Liaison for assistance. Publications Dicarboxylic Acid Separation by Dynamic and Size-Matched Recognition in Solution and in the Solid State Angewandte Chemie (International Ed. in English). Jan, 2018 | Pubmed ID: 29226498 Connectivity and Topology Invariance in Self-Assembled and Halogen-Bonded Anionic (6,3)-Networks Molecules (Basel, Switzerland). 11, 2017 | Pubmed ID: 29186793 Crystallographic Insights into the Self-assembly of KLVFF Amyloid-beta Peptides Biopolymers. Nov, 2017 | Pubmed ID: 29178159 Surface-Relief Gratings in Halogen-Bonded Polymer-Azobenzene Complexes: A Concentration-Dependence Study Molecules (Basel, Switzerland). Oct, 2017 | Pubmed ID: 29143770 Efficient Encapsulation of Fluorinated Drugs in the Confined Space of Water-Dispersible Fluorous Supraparticles Angewandte Chemie (International Ed. in English). Dec, 2017 | Pubmed ID: 29105938 Bioreducible Hydrophobin-Stabilized Supraparticles for Selective Intracellular Release ACS Nano. Sep, 2017 | Pubmed ID: 28806871 Halogenation Dictates the Architecture of Amyloid Peptide Nanostructures Nanoscale. Jul, 2017 | Pubmed ID: 28696473 Halogen Bonded Borromean Networks by Design: Topology Invariance and Metric Tuning in a Library of Multi-component Systems Chemical Science. Mar, 2017 | Pubmed ID: 28694953 Hierarchical Self-Assembly of Halogen-Bonded Block Copolymer Complexes into Upright Cylindrical Domains Chem. Mar, 2017 | Pubmed ID: 28367516 Crystallographic Insights into the Structural Aspects of Thioctic Acid Based Halogen-bond Donor for the Functionalization of Gold Nanoparticles Acta Crystallographica Section B, Structural Science, Crystal Engineering and Materials. Apr, 2017 | Pubmed ID: 28362288 Halogen Bonding Stabilizes a Cis-azobenzene Derivative in the Solid State: a Crystallographic Study Acta Crystallographica Section B, Structural Science, Crystal Engineering and Materials. Apr, 2017 | Pubmed ID: 28362286 Introduction to the Special Issue on Halogen Bonding Acta Crystallographica Section B, Structural Science, Crystal Engineering and Materials. 04, 2017 | Pubmed ID: 28362273 Nanostructure and Stability of Calcitonin Amyloids The Journal of Biological Chemistry. 05, 2017 | Pubmed ID: 28283568 Rotational Dynamics of Diazabicyclo[2.2.2]octane in Isomorphous Halogen-Bonded Co-crystals: Entropic and Enthalpic Effects Journal of the American Chemical Society. Jan, 2017 | Pubmed ID: 27991779 Superfluorinated and NIR-luminescent Gold Nanoclusters Chemical Communications (Cambridge, England). 01, 2017 | Pubmed ID: 27982144 Crystal Structure of the DFNKF Segment of Human Calcitonin Unveils Aromatic Interactions Between Phenylalanines Chemistry (Weinheim an Der Bergstrasse, Germany). Feb, 2017 | Pubmed ID: 27806188 Efficient Light-Induced Phase Transitions in Halogen-Bonded Liquid Crystals Chemistry of Materials : a Publication of the American Chemical Society. 11, 2016 | Pubmed ID: 27917024 Natural AbundanceN AndC Solid-State NMR Chemical Shifts: High Sensitivity Probes of the Halogen Bond Geometry Chemistry (Weinheim an Der Bergstrasse, Germany). Nov, 2016 | Pubmed ID: 27709719 Activation of Cell-Penetrating Peptides with Ionpair-π Interactions and Fluorophiles Journal of the American Chemical Society. Sep, 2016 | Pubmed ID: 27568814 Design of Highly Stable Echogenic Microbubbles Through Controlled Assembly of Their Hydrophobin Shell Angewandte Chemie (International Ed. in English). Aug, 2016 | Pubmed ID: 27461549 Superfluorinated Ionic Liquid Crystals Based on Supramolecular, Halogen-Bonded Anions Angewandte Chemie (International Ed. in English). May, 2016 | Pubmed ID: 27073033 The Halogen Bond Chemical Reviews. Feb, 2016 | Pubmed ID: 26812185 Halogen Bonding in Hypervalent Iodine Compounds Topics in Current Chemistry. 2016 | Pubmed ID: 26809623 Atomistic Simulation of Hydrophobin HFBII Conformation in Aqueous and Fluorous Media and at the Water/vacuum Interface Journal of Molecular Graphics & Modelling. Jan, 2016 | Pubmed ID: 26606320 Dynamic Characterization of Crystalline Supramolecular Rotors Assembled Through Halogen Bonding Journal of the American Chemical Society. Dec, 2015 | Pubmed ID: 26583701 Nanomedicine Delivery: Does Protein Corona Route to the Target or off Road? Nanomedicine (London, England). 2015 | Pubmed ID: 26470748 Supramolecular Amplification of Amyloid Self-assembly by Iodination Nature Communications. Jun, 2015 | Pubmed ID: 26123690 Halogen-Bond-Assisted Guest Inclusion in a Synthetic Cavity Angewandte Chemie (International Ed. in English). Jul, 2015 | Pubmed ID: 26012524 A Synthetically Modified Hydrophobin Showing Enhanced Fluorous Affinity Journal of Colloid and Interface Science. Jun, 2015 | Pubmed ID: 25725398 Halogen Bond: a Long Overlooked Interaction Topics in Current Chemistry. 2015 | Pubmed ID: 25504313 (19)F Magnetic Resonance Imaging (MRI): from Design of Materials to Clinical Applications Chemical Reviews. Jan, 2015 | Pubmed ID: 25329814 Orthogonal Halogen and Hydrogen Bonds Involving a Peptide Bond Model†Electronic Supplementary Information (ESI) Available: Experimental Part, DSC, IR Spectroscopic and Crystallographic Data. CCDC 899779-899785. For ESI and Crystallographic Data in CIF or Other Electronic Format See DOI: 10.1039/c4ce01514bClick Here for Additional Data File.Click Here for Additional Data File CrystEngComm. Sep, 2014 | Pubmed ID: 25663816 Type II Halogen···halogen Contacts Are Halogen Bonds IUCrJ. Jan, 2014 | Pubmed ID: 25075314 Halogen-bonded Mesogens Direct Polymer Self-assemblies Up to Millimetre Length Scale Nature Communications. Jun, 2014 | Pubmed ID: 24893843 A Superfluorinated Molecular Probe for Highly Sensitive in Vivo(19)F-MRI Journal of the American Chemical Society. Jun, 2014 | Pubmed ID: 24884816 The 1:1 Co-crystal of Triphen-yl(2,3,5,6-tetra-fluoro-benz-yl)phospho-nium Bromide and 1,1,2,2-tetra-fluoro-1,2-di-iodo-ethane Acta Crystallographica. Section E, Structure Reports Online. Jan, 2014 | Pubmed ID: 24527019 Azobenzene-based Difunctional Halogen-bond Donor: Towards the Engineering of Photoresponsive Co-crystals Acta Crystallographica Section B, Structural Science, Crystal Engineering and Materials. Feb, 2014 | Pubmed ID: 24441138 Different Permeability of Potassium Salts Across the Blood-brain Barrier Follows the Hofmeister Series PloS One. 2013 | Pubmed ID: 24205257 (4,7,13,16,21,24-Hexaoxa-1,10-di-aza-bicyclo-[8.8.8]hexa-cosa-ne)sodium Iodide-1,1,2,2,tetra-fluoro-1,2-diiodo-ethane (2/3) Acta Crystallographica. Section E, Structure Reports Online. 2013 | Pubmed ID: 24046565 The Halogen Bond in the Design of Functional Supramolecular Materials: Recent Advances Accounts of Chemical Research. Nov, 2013 | Pubmed ID: 23805801 Tetra-phenyl-phospho-nium Iodide-1,3,5-tri-fluoro-2,4,6-tri-iodo-benzene-methanol (3/4/1) Acta Crystallographica. Section E, Structure Reports Online. Jun, 2013 | Pubmed ID: 23795046 (Tris{2-[2-(2,3,5,6-tetra-fluoro-4-iodo-phen-oxy)eth-oxy]eth-yl}amine)-potassium Iodide Acta Crystallographica. Section E, Structure Reports Online. May, 2013 | Pubmed ID: 23723785 [5,11,17,23-Tetra-tert-butyl-25,27-(3,6-dioxaoctan-1,8-di-oxy)-26,28-bis-(pyridin-2-ylmeth-oxy)calix[4]arene]sodium Iodide-1,2,4,5-tetra-fluoro-3,6-diiodo-benzene-methanol (2/3/4) Acta Crystallographica. Section E, Structure Reports Online. May, 2013 | Pubmed ID: 23723756 1,3-Bis(2,3,5,6-tetra-fluoro-4-iodo-phen-oxy)-2,2-bis-[(2,3,5,6-tetra-fluoro-4-iodo-phen-oxy)meth-yl]propane Acta Crystallographica. Section E, Structure Reports Online. Apr, 2013 | Pubmed ID: 23634113 Halogen Bonding and Pharmaceutical Cocrystals: the Case of a Widely Used Preservative Molecular Pharmaceutics. May, 2013 | Pubmed ID: 23514087 The Halogen-bonded Adduct 1,4-bis(pyri-din-4-yl)buta-1,3-diyne-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-hexa-deca-fluoro-1,8-diiodo-octane (1/1) Acta Crystallographica. Section E, Structure Reports Online. Mar, 2013 | Pubmed ID: 23476525 Self-assembly of Pyridine-modified Lipoic Acid Derivatives on Gold and Their Interaction with Thyroxine (t4) International Journal of Molecular Sciences. Feb, 2013 | Pubmed ID: 23389045 Metal-bound Halogen Atoms in Crystal Engineering Chemical Communications (Cambridge, England). Mar, 2013 | Pubmed ID: 23358582 Halogen-bonding-triggered Supramolecular Gel Formation Nature Chemistry. Jan, 2013 | Pubmed ID: 23247176 Enzyme Mimics: Halogen and Chalcogen Team Up Nature Chemistry. May, 2012 | Pubmed ID: 22614374 2-Iodo-imidazolium Receptor Binds Oxoanions Via Charge-assisted Halogen Bonding Organic & Biomolecular Chemistry. Feb, 2012 | Pubmed ID: 22218406 The Fluorous Effect in Biomolecular Applications Chemical Society Reviews. Jan, 2012 | Pubmed ID: 21691620 Trends in Biomedical Engineering: Focus on Smart Bio-Materials and Drug Delivery Journal of Applied Biomaterials & Biomechanics : JABB. May-Aug, 2011 | Pubmed ID: 22065386 Tracing Iodine Nature Chemistry. Mar, 2011 | Pubmed ID: 21336335 Halogen Bonding: a General Route in Anion Recognition and Coordination Chemical Society Reviews. Oct, 2010 | Pubmed ID: 20734002 Dimensional Encapsulation of I(-)...I(2)...I(-) in an Organic Salt Crystal Matrix Chemical Communications (Cambridge, England). Apr, 2010 | Pubmed ID: 20369162 Nonporous Organic Solids Capable of Dynamically Resolving Mixtures of Diiodoperfluoroalkanes Science (New York, N.Y.). Mar, 2009 | Pubmed ID: 19286551 Binding Energies and 19F Nuclear Magnetic Deshielding in Paramagnetic Halogen-bonded Complexes of TEMPO with Haloperfluorocarbons The Journal of Physical Chemistry. A. Oct, 2008 | Pubmed ID: 18795762 Chemistry. Halogen Versus Hydrogen Science (New York, N.Y.). Aug, 2008 | Pubmed ID: 18703728 Halogen Bonding in Supramolecular Chemistry Angewandte Chemie (International Ed. in English). 2008 | Pubmed ID: 18651626 Mutual Induced Coordination in Halogen-bonded Anionic Assemblies with (6,3) Cation-templated Topologies Chemical Communications (Cambridge, England). Apr, 2008 | Pubmed ID: 18368148 2-(2,3,5,6-Tetra-fluoro-4-iodo-anilino)-ethanol Acta Crystallographica. Section E, Structure Reports Online. Dec, 2007 | Pubmed ID: 21200777 Highly Interpenetrated Supramolecular Networks Supported by N...I Halogen Bonding Chemistry (Weinheim an Der Bergstrasse, Germany). 2007 | Pubmed ID: 17407111 Fluorinated Liquid Crystals Formed by Halogen Bonding Chemical Communications (Cambridge, England). Aug, 2006 | Pubmed ID: 16883413 A Halogen-bonding-based Heteroditopic Receptor for Alkali Metal Halides Journal of the American Chemical Society. Nov, 2005 | Pubmed ID: 16248605 Halogen Bonding Based Recognition Processes: a World Parallel to Hydrogen Bonding Accounts of Chemical Research. May, 2005 | Pubmed ID: 15895976 From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding Gabriella Cavallo1, Duncan W. Bruce2, Giancarlo Terraneo1, Giuseppe Resnati3, Pierangelo Metrangolo1 1Laboratory of Supramolecular and Bio-Nanomaterials (SBNLab), Department of Chemistry, Materials, and Chemical Engineering "Giulio Natta", Politecnico di Milano, 2Department of Chemistry, University of York, 3Laboratory of Nanostructured Fluorinated Materials (NFMLab), Department of Chemistry, Materials, and Chemical Engineering "Giulio Natta", Politecnico di Milano JoVE 55636 Chimica
From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding Gabriella Cavallo1, Duncan W. Bruce2, Giancarlo Terraneo1, Giuseppe Resnati3, Pierangelo Metrangolo1 1Laboratory of Supramolecular and Bio-Nanomaterials (SBNLab), Department of Chemistry, Materials, and Chemical Engineering "Giulio Natta", Politecnico di Milano, 2Department of Chemistry, University of York, 3Laboratory of Nanostructured Fluorinated Materials (NFMLab), Department of Chemistry, Materials, and Chemical Engineering "Giulio Natta", Politecnico di Milano JoVE 55636 Chimica