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JoVE Journal Chemistry
Versatile CO2 Transformations into Complex Products
 

Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy

Article DOI: 10.3791/60348-v • 07:36 min • November 9th, 2019
November 9th, 2019 •
*1,2, *1, 1, 1
1LCC-CNRS, Université de Toulouse, CNRS, 2LISBP, Université de Toulouse, CNRS, INRA, INSA
* These authors contributed equally

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Automatic Translation

CO2 transformations are conducted in a one-pot two-step procedure for the synthesis of complex molecules. The selective 4 e- reduction of CO2 with a hydroborane reductant affords a reactive and versatile bis(boryl)acetal intermediate which is subsequently involved in condensation reaction or carbene-mediated C-C coupling generation.

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Keywords: CO2 Transformations One-pot Two-step Strategy Cascade Reactions CO2 Reduction Intermediate Reactivity Compound Synthesis Glove Box Gas Handling NMR Analysis Iron Catalyst 9-BBN 2,6-diisopropylethylamine Tetrahydrofuran
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