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Chapters
- 00:04Title
- 00:49Sodium Thiomethoxide (CH3SNa) Synthesis
- 03:092,3,6,7,10,11-Hexakis(pentanoylthio)triphenylene (HVaTT) Synthesis
- 07:45Lead 2,3,6,7,10,11-Triphenylene Hexathiol (HTT-Pb) Framework Single Crystal Synthesis and Interaction with Paraquat Diiodide
- 10:13Results: HVaTT and HTT-Pb ([Pb3OH0.5(HTT)]-1.5) Characterization
- 11:47Conclusion
Here, we present a one-pot, transition-metal-free synthesis of thiols and thioesters from aromatic halides and sodium thiomethoxide, followed by the preparation of single crystals of a metal-dithiolene network using thiol species generated in situ from the more stable and tractable thioester.
