Journal
/
Química
/
High-pressure Sapphire Cell for Phase Equilibria Measurements of CO2/Organic/Water Systems
JoVE Journal
Química
É necessária uma assinatura da JoVE para visualizar este conteúdo.  Faça login ou comece sua avaliação gratuita.
JoVE Journal Química
High-pressure Sapphire Cell for Phase Equilibria Measurements of CO2/Organic/Water Systems

High-pressure Sapphire Cell for Phase Equilibria Measurements of CO2/Organic/Water Systems

DOI:
10.3791/51378-v

•

05:46 min

•

January 24, 2014

•

, , , ,
1School of Chemistry and Biochemistry,Georgia Institute of Technology, 2School of Chemical and Biomolecular Engineering,Georgia Institute of Technology

Capítulos

  • 00:05Título
  • 00:57Pressure-test the Sapphire Cell Every 12 Pressure Cycles
  • 01:57Operation of the Sapphire Cell Apparatus
  • 04:31Results: CO2/THF/Water or CO2/ACN/Water Equilibria
  • 05:22Conclusion

Summary

Tadução automática

Tadução automática

The high pressure sapphire cell apparatus is a unique tool to study, without sampling, phase behavior under a wide range of pressures. Using a cathetometer, very precise volume measurements can be recorded to measure liquid expansion and phase composition. Thus, this synthetic method enables the study of (1) phase equilibria of multi-component mixtures and (2) the partition behavior of catalyst or model compounds as a function of pressure.

Tags

High-pressure Sapphire CellPhase EquilibriaCO2/organic/water SystemsTernary Phase DiagramsTHF-water-CO2 SystemGas-expanded LiquidsGas-expanded Ionic LiquidsOrganic Aqueous Tunable Systems (OATS)Phase BehaviorPhase CompositionCatalyst Partitioning

Article

Embed

ADICIONAR À PLAYLIST

Usage Statistics

Vídeos Relacionados

check_url/pt/51378?article_type=v

Determination of the Gas-phase Acidities of Oligopeptides
check_url/pt/51378?article_type=v

Synthetic Methodology for Asymmetric Ferrocene Derived Bio-conjugate Systems via Solid Phase Resin-based Methodology
check_url/pt/51378?article_type=v

Dissolution Dynamic Nuclear Polarization Instrumentation for Real-time Enzymatic Reaction Rate Measurements by NMR
check_url/pt/51378?article_type=v

High Pressure Single Crystal Diffraction at PX^2
check_url/pt/51378?article_type=v

A Straightforward Method for Glucosinolate Extraction and Analysis with High-pressure Liquid Chromatography (HPLC)
check_url/pt/51378?article_type=v

Measurements of Long-range Electronic Correlations During Femtosecond Diffraction Experiments Performed on Nanocrystals of Buckminsterfullerene
check_url/pt/51378?article_type=v

A Convenient Method for Extraction and Analysis with High-Pressure Liquid Chromatography of Catecholamine Neurotransmitters and Their Metabolites
check_url/pt/51378?article_type=v

Chemical Synthesis of Porous Barium Titanate Thin Film and Thermal Stabilization of Ferroelectric Phase by Porosity-Induced Strain
check_url/pt/51378?article_type=v

Development and Validation of Chromium Getters for Solid Oxide Fuel Cell Power Systems
check_url/pt/51378?article_type=v

Solid Phase 11C-Methylation, Purification and Formulation for the Production of PET Tracers

Read Article