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Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance
 

Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance

Article DOI: 10.3791/58052-v • 08:12 min • September 5th, 2018
September 5th, 2018 •
1, 2, 1, 1, 2, 1
1Instituto de Ciencia Molecular (ICMol), Universitat de València, 2Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC and The Barcelona Institute of Science and Technology

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Resumo
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Robust functional catechol coatings were produced in one step by direct reaction of the material known as HKUST with synthetic catechols under anaerobic conditions. The formation of homogeneous coatings surrounding the entire crystal is ascribed to the biomimetic catalytic activity of Cu(II) dimers on the external surface of the crystals.

Tags

Surface Functionalization Metal-organic Frameworks Moisture Resistance Water Stability Hydrophobicity Modification Coating Functionality Catalytic Open Metal Sites Polymerization Catechol Molecules Porosity Reaction Conditions Glass Vial Spatulas Micropipette Hdcat Anhydrous Chloroform HKUST Sonication Oven Centrifuge Tube
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