Journal
/
Chemistry
/
Preparation of Hydrophobic Metal-Organic Frameworks via Plasma Enhanced Chemical Vapor Deposition of Perfluoroalkanes for the Removal of Ammonia
JoVE Journal
Chemistry
A subscription to JoVE is required to view this content.  Sign in or start your free trial.
JoVE Journal Chemistry
Preparation of Hydrophobic Metal-Organic Frameworks via Plasma Enhanced Chemical Vapor Deposition of Perfluoroalkanes for the Removal of Ammonia

Preparation of Hydrophobic Metal-Organic Frameworks via Plasma Enhanced Chemical Vapor Deposition of Perfluoroalkanes for the Removal of Ammonia

DOI:
10.3791/51175-v

•

12:05 min

•

October 10, 2013

•

,
1Research and Development,Science Applications International Corporation (SAIC), 2Edgewood Chemical Biological Center,Research Development Engineering Command

Chapters

  • 00:05Title
  • 01:31Cu-BTC Synthesis and Preparation
  • 03:09Plasma Enhanced Chemical Vapor Deposition of Perfluoroalkanes on Cu-BTC
  • 05:23Aging of Cu-BTC under Humid Conditions and Ammonia Microbreakthrough Experiments
  • 08:07Results: Characterization of Perfluoroalkane Plasma Treated Metal-Organic Frameworks
  • 11:07Conclusion

Summary

Automatic Translation

Automatic Translation

Herein the procedures for plasma enhanced chemical vapor deposition of perfluoroalkanes on microporous materials such as metal-organic frameworks to enhance their stability and hydrophobicity are described. Furthermore, breakthrough testing of milligram quantities of samples is described in detail.

Tags

Metal-organic FrameworksMOFsPlasma Enhanced Chemical Vapor DepositionPECVDPerfluoroalkanesHydrophobicCu-BTCHKUST-1Ammonia RemovalMicroporous MaterialsSurface AreaHumid ConditionsMicrobreakthrough Experiments

Article

Embed

ADD TO PLAYLIST

Usage Statistics

Related Videos

check_url/51175?article_type=v

Synthesis and Characterization of Functionalized Metal-organic Frameworks
check_url/51175?article_type=v

Chemical Vapor Deposition of an Organic Magnet, Vanadium Tetracyanoethylene
check_url/51175?article_type=v

Epitaxial Growth of Perovskite Strontium Titanate on Germanium via Atomic Layer Deposition
check_url/51175?article_type=v

Aerosol-assisted Chemical Vapor Deposition of Metal Oxide Structures: Zinc Oxide Rods
check_url/51175?article_type=v

Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance
check_url/51175?article_type=v

Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks (MOFs)
check_url/51175?article_type=v

Synthesis of Single-Crystalline Core-Shell Metal-Organic Frameworks
check_url/51175?article_type=v

A Technical Guide for Performing Spectroscopic Measurements on Metal-Organic Frameworks
check_url/51175?article_type=v

Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers (Video) | JoVE

check_url/51175?article_type=v

Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks (Video) | JoVE

Read Article