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効率的な薬物のような Bispirocyclic を介して α イミノ γ-ラクトンの有機触媒及び Alkylidene ピラゾロン足場の構築
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JoVE Journal
Chemistry
Efficient Construction of Drug-like Bispirocyclic Scaffolds Via Organocatalytic Cycloadditions of α-Imino γ-Lactones and Alkylidene Pyrazolones
Please note that all translations are automatically generated.
Click here for the English version.
効率的な薬物のような Bispirocyclic を介して α イミノ γ-ラクトンの有機触媒及び Alkylidene ピラゾロン足場の構築
DOI:
10.3791/59155-v
•
10:17 min
•
February 07, 2019
•
Yani Zhou
,
Nannan Chen
,
Yaping Cheng
,
Xiaoqing Cai
1
School of Basic Medical Sciences
,
Lanzhou University
,
2
School of Pharmaceutical Sciences
,
Sun Yat-sen University
Chapters
00:04
Title
01:07
Preparation of α-Arylidiene Pyrazolinone Species
06:38
Asymmetric Synthesis of Bispirocyclic Compounds
08:00
Results: Synthesis and Characterization of Enantiomerically Enriched Bispirocyclic Scaffolds
09:22
Conclusion
Summary
Automatic Translation
English (Original)
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Automatic Translation
不斉濃縮 bispiro [γ-ブチロラクトン-pyrrolidin-4、4'-ピラゾロン] スケルトン非対称的、単純な有機触媒 1, 3-双極子付加環化反応により合成されます。
Tags
Keyword Extraction:Drug-like Bispirocyclic Scaffolds
Organocatalytic Cycloadditions
α-imino γ-lactones
Alkylidene Pyrazolones
Bipolar Cycloaddition
Bispirocyclic Compounds
Natural Products
Biological Activities
Chiral Spiral Centers
High Yields
Stereoselectivity
Pyrazolone
Hydrazine
Ethyl Acetoacetate
α-arylidiene Pyrazolinone
Benzaldehyde
Magnesium Oxide
Acetonitrile
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