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Chemistry

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Microwave-assisted Intramolecular Dehydrogenative Diels-Alder Reactions for the Synthesis of Functionalized Naphthalenes/Solvatochromic Dyes
 

Microwave-assisted Intramolecular Dehydrogenative Diels-Alder Reactions for the Synthesis of Functionalized Naphthalenes/Solvatochromic Dyes

Article DOI: 10.3791/50511-v 12:07 min April 1st, 2013
April 1st, 2013

챕터

요약

Microwave-assisted intramolecular dehydrogenative Diels-Alder (DA) reactions provide concise access to functionalized cyclopenta[b]naphthalene building blocks. The utility of this methodology is demonstrated by one-step conversion of the dehydrogenative DA cycloadducts into novel solvatochromic fluorescent dyes via Buchwald-Hartwig palladium-catalyzed cross-coupling reactions.

Tags

Keywords: Microwave-assisted Intramolecular Dehydrogenative Diels-Alder Reactions Functionalized Naphthalenes Solvatochromic Dyes Cyclopenta[b]naphthalenes Buchwald-Hartwig Palladium-catalyzed Cross-coupling Fluorescence Spectroscopy
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