Dhandapani V. Sadasivam Department of Chemistry Lehigh University Biography Publications Institution JoVE Articles Dhandapani V. Sadasivam has not added a biography. If you are Dhandapani V. Sadasivam and would like to personalize this page please email our Author Liaison for assistance. Publications Catalytic, Atom-economical Radical Arylation of Epoxides Angewandte Chemie (International Ed. in English). May, 2012 | Pubmed ID: 22461392 Catalytic Ni(II) in Reactions of SmI2: Sm(II)- or Ni(0)-based Chemistry? Journal of the American Chemical Society. Jul, 2011 | Pubmed ID: 21619012 A Convenient Pathway to Sm(II)-mediated Chemistry in Acetonitrile Organic & Biomolecular Chemistry. Mar, 2011 | Pubmed ID: 21321772 Uncovering the Mechanistic Role of HMPA in the Samarium Barbier Reaction Journal of the American Chemical Society. Nov, 2010 | Pubmed ID: 21090625 Corrigendum to Solvent-dependent Oxidative Coupling of 1-aryl-1,3-dicarbonyls and Styrene Tetrahedron. Jul, 2010 | Pubmed ID: 20806051 Dynamic Ligand Exchange in Reactions of Samarium Diiodide Organic Letters. Sep, 2010 | Pubmed ID: 20722385 Solvent-dependent Oxidative Coupling of 1-aryl-1,3-dicarbonyls and Styrene Tetrahedron. Dec, 2009 | Pubmed ID: 20625455 Studies on the Mechanism, Selectivity, and Synthetic Utility of Lactone Reduction Using SmI(2) and H(2)O Journal of the American Chemical Society. Oct, 2009 | Pubmed ID: 19764763 Mechanistic Study of Samarium Diiodide-HMPA Initiated 5-exo-trig Ketyl-Olefin Coupling: the Role of HMPA in Post-electron Transfer Steps Journal of the American Chemical Society. Jun, 2008 | Pubmed ID: 18479133 A Computational Study of the Formation and Dimerization of Benzothiet-2-one Organic Letters. Jan, 2008 | Pubmed ID: 18092791 Stopped-flow Kinetics of Tetrazine Cycloadditions; Experimental and Computational Studies Toward Sequential Transition States The Journal of Physical Chemistry. A. Feb, 2006 | Pubmed ID: 16435789 A Theoretical Study of the [4 + 4] Dimerization of Thioformylketene Organic Letters. Dec, 2005 | Pubmed ID: 16354074 Preparation and Use of Samarium Diiodide (SmI2) in Organic Synthesis: The Mechanistic Role of HMPA and Ni(II) Salts in the Samarium Barbier Reaction Dhandapani V. Sadasivam1, Kimberly A. Choquette1, Robert A. Flowers II1 1Department of Chemistry, Lehigh University JoVE 4323 Química
Preparation and Use of Samarium Diiodide (SmI2) in Organic Synthesis: The Mechanistic Role of HMPA and Ni(II) Salts in the Samarium Barbier Reaction Dhandapani V. Sadasivam1, Kimberly A. Choquette1, Robert A. Flowers II1 1Department of Chemistry, Lehigh University JoVE 4323 Química