Slavi C. Sevov Department of Chemistry and Biochemistry University of Notre Dame Biography Publications Institution JoVE Articles Slavi C. Sevov has not added a biography. If you are Slavi C. Sevov and would like to personalize this page please email our Author Liaison for assistance. Publications Rational Synthesis of [Ge(9){Si(SiMe(3))(3)}(3)](-) from Its Parent Zintl Ion Ge(9)(4-) Inorganic Chemistry. Jan, 2012 | Pubmed ID: 22288571 Hydrogen-bonded Inclusion Compounds with Reversed Polarity: Anionic Metal-complexes and Cationic Organic Linkers Inorganic Chemistry. Dec, 2011 | Pubmed ID: 22085246 Metal-centered Deltahedral Zintl Ions: Synthesis of [Ni@Sn9]4- by Direct Extraction from Intermetallic Precursors and of the Vertex-fused Dimer [{Ni@Sn8(μ-Ge)(1/2)}2]4- Inorganic Chemistry. Nov, 2011 | Pubmed ID: 22026406 "n-Doping" of Deltahedral Zintl Ions Journal of the American Chemical Society. May, 2011 | Pubmed ID: 21476584 Addition of a Thallium Vertex to Empty and Centered Nine-atom Deltahedral Zintl Ions of Germanium and Tin Inorganic Chemistry. Mar, 2011 | Pubmed ID: 21294520 The Elusive Closo-Ge(10)(2-) Zintl Ion: Finally "captured" As a Ligand in the Complex [Ge(10)Mn(CO)(4)](3-) Inorganic Chemistry. Jul, 2010 | Pubmed ID: 20552962 Heteroatomic Deltahedral Zintl Ions of Group 14 and Their Alkenylation Inorganic Chemistry. Jan, 2010 | Pubmed ID: 20000832 Isolated Co15 Clusters and Their Assembly into a 3D Network: Conformation-directed Synthesis Inorganic Chemistry. Sep, 2009 | Pubmed ID: 19658400 Metal-organic Frameworks with Direct Transition Metal-sulfonate Interactions and Charge-assisted Hydrogen Bonds Inorganic Chemistry. Jul, 2009 | Pubmed ID: 19537705 Functionalization of Nine-atom Deltahedral Zintl Ions with Organic Substituents: Detailed Studies of the Reactions Journal of the American Chemical Society. Jul, 2009 | Pubmed ID: 19496567 Tin-based Organo-Zintl Ions: Alkylation and Alkenylation of Sn9(4-) Inorganic Chemistry. Jul, 2008 | Pubmed ID: 18510308 Synthesis, Structures, and Magnetic Properties of Metal-coordination Polymers with Benzenepentacarboxylate Linkers Inorganic Chemistry. Feb, 2008 | Pubmed ID: 18095675 Organo-Zintl Clusters Soluble in Conventional Organic Solvents: Setting the Stage for Organo-Zintl Cluster Chemistry Inorganic Chemistry. Dec, 2007 | Pubmed ID: 18034475 Addition of Alkenes to Deltahedral Zintl Clusters by Reaction with Alkynes: Synthesis and Structure of [Fc-CH=CH-Ge9-CH=CH-Fc]2-, an Organo-zintl-organometallic Anion Angewandte Chemie (International Ed. in English). 2007 | Pubmed ID: 17661297 Heteroatomic Deltahedral Clusters: Synthesis and Structures of Closo-[Bi3Ni(4)(CO)6]3-, Closo-[Bi4Ni4(CO)6]2-, the Open Cluster [Bi3Ni6(CO)9]3-, and the Intermetalloid Closo-[Nix@[Bi6Ni6(CO)8)]4- Journal of the American Chemical Society. Jun, 2007 | Pubmed ID: 17550250 Hydrogen-bonded Metal-complex Sulfonate (MCS) Inclusion Compounds: Effect of the Guest Molecule on the Host Framework Inorganic Chemistry. May, 2007 | Pubmed ID: 17461580 In Search of Cyclohexane-like Sn6(12-): Synthesis of Li2Ln5Sn7 (Ln = Ce, Pr, Sm, Eu) with an Open-chain Heptane-like Sn7(16-) Instead Inorganic Chemistry. May, 2007 | Pubmed ID: 17428047 Alkylation of Deltahedral Zintl Clusters: Synthesis of [R-Ge9-Ge9-R]4- (R = TBu, SBu, NBu, TAm and Structure of [tBu-Ge9-Ge9-tBu]4- Inorganic Chemistry. Apr, 2007 | Pubmed ID: 17311378 [Zn9Bi11]5-: a Ligand-free Intermetalloid Cluster Angewandte Chemie (International Ed. in English). Aug, 2006 | Pubmed ID: 16819751 In Search of Benzene-like Sn6(6-): Synthesis of Na4CaSn6 with Interconnected Cyclohexane-like Sn6(6-) Inorganic Chemistry. May, 2006 | Pubmed ID: 16711698 Deltahedral Germanium Clusters: Insertion of Transition-metal Atoms and Addition of Organometallic Fragments Journal of the American Chemical Society. Mar, 2006 | Pubmed ID: 16551125 Analysis of the Effect of Spin-orbit Coupling on the Electronic Structure and Excitation Spectrum of the Bi2(2-) Anion in (K-crypt)2Bi2 on the Basis of Relativistic Electronic Structure Calculations The Journal of Physical Chemistry. A. Mar, 2005 | Pubmed ID: 16833492 Heavy-metal Aromatic and Conjugated Species: Rings, Oligomers, and Chains of Tin in Li(9)(-)(x)EuSn(6+)(x), Li(9)(-)(x)CaSn(6+)(x), Li(5)Ca(7)Sn(11), Li(6)Eu(5)Sn(9), LiMgEu(2)Sn(3), and LiMgSr(2)Sn(3) Inorganic Chemistry. Jul, 2005 | Pubmed ID: 16022534 [(Ni-Ni-Ni)@(Ge9)2]4-: a Linear Triatomic Nickel Filament Enclosed in a Dimer of Nine-atom Germanium Clusters Angewandte Chemie (International Ed. in English). Jun, 2005 | Pubmed ID: 15929153 [(Pd-Pd)@Ge18]4-: a Palladium Dimer Inside the Largest Single-cage Deltahedron Journal of the American Chemical Society. Jun, 2005 | Pubmed ID: 15913347 Ligand-free Deltahedral Clusters of Silicon in Solution: Synthesis, Structure, and Electrochemistry of Si9(2-) Inorganic Chemistry. Apr, 2005 | Pubmed ID: 15819550 Heavy-metal Aromatic Rings: Cyclopentadienyl Anion Analogues Sn5(6-) and Pb5(6-) in the Zintl Phases Na8BaPb6, Na8BaSn6, and Na8EuSn6 Inorganic Chemistry. Oct, 2004 | Pubmed ID: 15446901 Reversible Repositioning of Zinc Atoms Within Single Crystals of a Zinc Polycarboxylate with an Open-framework Structure Journal of the American Chemical Society. Sep, 2004 | Pubmed ID: 15327283 Rationally Functionalized Deltahedral Zintl Ions: Synthesis and Characterization of [Ge9-ER3]3-, [R3E-Ge9-ER3]2-, and [R3E-Ge9-Ge9-ER3]4- (E=Ge, Sn; R=Me, Ph) Chemistry (Weinheim an Der Bergstrasse, Germany). Aug, 2004 | Pubmed ID: 15281156 Synthesis, Characterization, and Electronic Structure of Ba5In4Bi5: an Acentric and One-electron Deficient Phase Chemistry (Weinheim an Der Bergstrasse, Germany). Aug, 2004 | Pubmed ID: 15281144 Naked Deltahedral Silicon Clusters in Solution: Synthesis and Characterization of Si9(3-) and Si5(2-) Journal of the American Chemical Society. Jun, 2004 | Pubmed ID: 15174843 Synthesis and Characterization of Transition-metal Zintl Phases: Cs24Nb2In12As18 and Cs13Nb2In6As10 with Isolated Complex Anions Inorganic Chemistry. Dec, 2003 | Pubmed ID: 14658914 Derivatization of Deltahedral Zintl Ions by Nucleophilic Addition: [Ph-Ge9-SbPh2]2- and [Ph2Sb-Ge9-Ge9-SbPh2]4- Journal of the American Chemical Society. Nov, 2003 | Pubmed ID: 14611242 Novel Mixed-valence Heteropolyoxometalates: a Molybdenum Diphosphonate Anion [MoV7MoVIO16(O3PPhPO3H)4]3- and Its One- and Two-dimensional Assemblies Inorganic Chemistry. Nov, 2003 | Pubmed ID: 14577801 [Ge9=Ge9=Ge9=Ge9]8-: a Linear Tetramer of Nine-atom Germanium Clusters, a Nanorod Inorganic Chemistry. Sep, 2003 | Pubmed ID: 12971742 [Mo5VMo7VIO30(BPO4)2(O3P-Ph)6]5-: a Phenyl-substituted Molybdenum(V/VI) Boro-phosphate Polyoxometalate Inorganic Chemistry. Mar, 2003 | Pubmed ID: 12611535 Synthesis and Characterization of Transition-metal Zintl Phases: K(10)NbInAs(6) and K(9)Nb(2)As(6) Inorganic Chemistry. Feb, 2003 | Pubmed ID: 12562206 Cubane with a Handle: [[In(3)As(4)Nb]-As](7-) in Cs(7)NbIn(3)As(5) Angewandte Chemie (International Ed. in English). Apr, 2002 | Pubmed ID: 12491269 Synthesis and Characterization of K(38)Nb(7)As(24) and Cs(9)Nb(2)As(6): the First Mixed-valence Transition-metal Zintl Phases Inorganic Chemistry. Nov, 2002 | Pubmed ID: 12401102 [Ge(9)=Ge(9)=Ge(9)](6-): a Linear Trimer of 27 Germanium Atoms Journal of the American Chemical Society. Sep, 2002 | Pubmed ID: 12224941 Synthesis and Characterization of [Mo(7)O(16)(O(3)PCH(2)PO(3))(3)]:(8-) a Mixed-valent Polyoxomolybdenum Diphosphonate Anion with Octahedrally and Tetrahedrally Coordinated Molybdenum Inorganic Chemistry. Jul, 2002 | Pubmed ID: 12132930 Niobium-arsenic Zintl Phases: A(6)NbAs(5) (A = K, Rb, Cs), K(6)NbTlAs(4), and K(8)NbPbAs(5) with Edge-bridged Niobium-centered Tetrahedra of Arsenic, [NbAs(4)M](n-) Where M = As, Tl, Pb Inorganic Chemistry. Jun, 2002 | Pubmed ID: 12033887 KBa(2)InAs(3) with Coexisting Monomers of [In(2)As(7)](13-) and Their One-dimensional Polymers Inorganic Chemistry. Apr, 2002 | Pubmed ID: 11952387 Naked Clusters of 56 Tin Atoms in the Solid State Journal of the American Chemical Society. Apr, 2002 | Pubmed ID: 11916421 [Ph(2)Bi-(Ge(9))-BiPh(2)](2-): a Deltahedral Zintl Ion Functionalized by Exo-bonded Ligands Journal of the American Chemical Society. Mar, 2002 | Pubmed ID: 11890785 A Reduced Polyoxomolybdenum Borophosphate Anion Related to the Wells-Dawson Clusters Journal of the American Chemical Society. Feb, 2002 | Pubmed ID: 11829590 Synthesis and Characterization of Cs(5)P[Mo(4)O(14)(OH)](2).2H(2)O: a New Molybdophosphate Cluster with Face-sharing MoO(6) Octahedra Inorganic Chemistry. Jan, 2002 | Pubmed ID: 11782155 Synthesis and Characterization of RbLi(7)Ge(8) with Isolated Closo- Angewandte Chemie (International Ed. in English). Apr, 2001 | Pubmed ID: 11317317 Arachno- Angewandte Chemie (International Ed. in English). Mar, 2001 | Pubmed ID: 11268100 Deltahedral Clusters in Neat Solids: Synthesis and Structure of the Zintl Phase Cs(4)Pb(9) with Discrete Pb(9)(4-) Clusters Inorganic Chemistry. Jul, 1998 | Pubmed ID: 11670498 Synthesis and Structure of the Zintl-Phase K(4)Pb(9) Containing Isolated Pb(9)(4)(-) Clusters of Two Different Geometries Inorganic Chemistry. Mar, 1998 | Pubmed ID: 11670346 Synthesis, Characterization, and Bonding of Heteroatomic Clusters: Na(13)Cd(20)E(7) (E = Pb, Sn), a Further Example of a Structure Containing Empty Icosahedra Without an Element of Group 13 Inorganic Chemistry. Sep, 1997 | Pubmed ID: 11670084 Co(5)BP(3)O(14): The First Borophosphate with Planar BO(3) Groups Connected to PO(4) Tetrahedra Inorganic Chemistry. Nov, 1996 | Pubmed ID: 11666863 Синтез девять атомов Deltahedral Zintl ионы германия и их функционализации с органическими группами Miriam M. Gillett-Kunnath1, Slavi C. Sevov1 1Department of Chemistry and Biochemistry, University of Notre Dame JoVE 3532 Biologia
Синтез девять атомов Deltahedral Zintl ионы германия и их функционализации с органическими группами Miriam M. Gillett-Kunnath1, Slavi C. Sevov1 1Department of Chemistry and Biochemistry, University of Notre Dame JoVE 3532 Biologia