Slavi C. Sevov Department of Chemistry and Biochemistry University of Notre Dame Biography Publications Institution JoVE Articles Slavi C. Sevov has not added a biography. If you are Slavi C. Sevov and would like to personalize this page please email our Author Liaison for assistance. Publications Rational Synthesis of [Ge(9){Si(SiMe(3))(3)}(3)](-) from Its Parent Zintl Ion Ge(9)(4-) Inorganic Chemistry. Jan, 2012 | Pubmed ID: 22288571 Hydrogen-bonded Inclusion Compounds with Reversed Polarity: Anionic Metal-complexes and Cationic Organic Linkers Inorganic Chemistry. Dec, 2011 | Pubmed ID: 22085246 Metal-centered Deltahedral Zintl Ions: Synthesis of [Ni@Sn9]4- by Direct Extraction from Intermetallic Precursors and of the Vertex-fused Dimer [{Ni@Sn8(μ-Ge)(1/2)}2]4- Inorganic Chemistry. Nov, 2011 | Pubmed ID: 22026406 "n-Doping" of Deltahedral Zintl Ions Journal of the American Chemical Society. May, 2011 | Pubmed ID: 21476584 Addition of a Thallium Vertex to Empty and Centered Nine-atom Deltahedral Zintl Ions of Germanium and Tin Inorganic Chemistry. Mar, 2011 | Pubmed ID: 21294520 The Elusive Closo-Ge(10)(2-) Zintl Ion: Finally "captured" As a Ligand in the Complex [Ge(10)Mn(CO)(4)](3-) Inorganic Chemistry. Jul, 2010 | Pubmed ID: 20552962 Heteroatomic Deltahedral Zintl Ions of Group 14 and Their Alkenylation Inorganic Chemistry. Jan, 2010 | Pubmed ID: 20000832 Isolated Co15 Clusters and Their Assembly into a 3D Network: Conformation-directed Synthesis Inorganic Chemistry. Sep, 2009 | Pubmed ID: 19658400 Metal-organic Frameworks with Direct Transition Metal-sulfonate Interactions and Charge-assisted Hydrogen Bonds Inorganic Chemistry. Jul, 2009 | Pubmed ID: 19537705 Functionalization of Nine-atom Deltahedral Zintl Ions with Organic Substituents: Detailed Studies of the Reactions Journal of the American Chemical Society. Jul, 2009 | Pubmed ID: 19496567 Tin-based Organo-Zintl Ions: Alkylation and Alkenylation of Sn9(4-) Inorganic Chemistry. Jul, 2008 | Pubmed ID: 18510308 Synthesis, Structures, and Magnetic Properties of Metal-coordination Polymers with Benzenepentacarboxylate Linkers Inorganic Chemistry. Feb, 2008 | Pubmed ID: 18095675 Organo-Zintl Clusters Soluble in Conventional Organic Solvents: Setting the Stage for Organo-Zintl Cluster Chemistry Inorganic Chemistry. Dec, 2007 | Pubmed ID: 18034475 Addition of Alkenes to Deltahedral Zintl Clusters by Reaction with Alkynes: Synthesis and Structure of [Fc-CH=CH-Ge9-CH=CH-Fc]2-, an Organo-zintl-organometallic Anion Angewandte Chemie (International Ed. in English). 2007 | Pubmed ID: 17661297 Heteroatomic Deltahedral Clusters: Synthesis and Structures of Closo-[Bi3Ni(4)(CO)6]3-, Closo-[Bi4Ni4(CO)6]2-, the Open Cluster [Bi3Ni6(CO)9]3-, and the Intermetalloid Closo-[Nix@[Bi6Ni6(CO)8)]4- Journal of the American Chemical Society. Jun, 2007 | Pubmed ID: 17550250 Hydrogen-bonded Metal-complex Sulfonate (MCS) Inclusion Compounds: Effect of the Guest Molecule on the Host Framework Inorganic Chemistry. May, 2007 | Pubmed ID: 17461580 In Search of Cyclohexane-like Sn6(12-): Synthesis of Li2Ln5Sn7 (Ln = Ce, Pr, Sm, Eu) with an Open-chain Heptane-like Sn7(16-) Instead Inorganic Chemistry. May, 2007 | Pubmed ID: 17428047 Alkylation of Deltahedral Zintl Clusters: Synthesis of [R-Ge9-Ge9-R]4- (R = TBu, SBu, NBu, TAm and Structure of [tBu-Ge9-Ge9-tBu]4- Inorganic Chemistry. Apr, 2007 | Pubmed ID: 17311378 [Zn9Bi11]5-: a Ligand-free Intermetalloid Cluster Angewandte Chemie (International Ed. in English). Aug, 2006 | Pubmed ID: 16819751 In Search of Benzene-like Sn6(6-): Synthesis of Na4CaSn6 with Interconnected Cyclohexane-like Sn6(6-) Inorganic Chemistry. May, 2006 | Pubmed ID: 16711698 Deltahedral Germanium Clusters: Insertion of Transition-metal Atoms and Addition of Organometallic Fragments Journal of the American Chemical Society. Mar, 2006 | Pubmed ID: 16551125 Analysis of the Effect of Spin-orbit Coupling on the Electronic Structure and Excitation Spectrum of the Bi2(2-) Anion in (K-crypt)2Bi2 on the Basis of Relativistic Electronic Structure Calculations The Journal of Physical Chemistry. A. Mar, 2005 | Pubmed ID: 16833492 Heavy-metal Aromatic and Conjugated Species: Rings, Oligomers, and Chains of Tin in Li(9)(-)(x)EuSn(6+)(x), Li(9)(-)(x)CaSn(6+)(x), Li(5)Ca(7)Sn(11), Li(6)Eu(5)Sn(9), LiMgEu(2)Sn(3), and LiMgSr(2)Sn(3) Inorganic Chemistry. Jul, 2005 | Pubmed ID: 16022534 [(Ni-Ni-Ni)@(Ge9)2]4-: a Linear Triatomic Nickel Filament Enclosed in a Dimer of Nine-atom Germanium Clusters Angewandte Chemie (International Ed. in English). Jun, 2005 | Pubmed ID: 15929153 [(Pd-Pd)@Ge18]4-: a Palladium Dimer Inside the Largest Single-cage Deltahedron Journal of the American Chemical Society. Jun, 2005 | Pubmed ID: 15913347 Ligand-free Deltahedral Clusters of Silicon in Solution: Synthesis, Structure, and Electrochemistry of Si9(2-) Inorganic Chemistry. Apr, 2005 | Pubmed ID: 15819550 Heavy-metal Aromatic Rings: Cyclopentadienyl Anion Analogues Sn5(6-) and Pb5(6-) in the Zintl Phases Na8BaPb6, Na8BaSn6, and Na8EuSn6 Inorganic Chemistry. Oct, 2004 | Pubmed ID: 15446901 Reversible Repositioning of Zinc Atoms Within Single Crystals of a Zinc Polycarboxylate with an Open-framework Structure Journal of the American Chemical Society. Sep, 2004 | Pubmed ID: 15327283 Rationally Functionalized Deltahedral Zintl Ions: Synthesis and Characterization of [Ge9-ER3]3-, [R3E-Ge9-ER3]2-, and [R3E-Ge9-Ge9-ER3]4- (E=Ge, Sn; R=Me, Ph) Chemistry (Weinheim an Der Bergstrasse, Germany). Aug, 2004 | Pubmed ID: 15281156 Synthesis, Characterization, and Electronic Structure of Ba5In4Bi5: an Acentric and One-electron Deficient Phase Chemistry (Weinheim an Der Bergstrasse, Germany). Aug, 2004 | Pubmed ID: 15281144 Naked Deltahedral Silicon Clusters in Solution: Synthesis and Characterization of Si9(3-) and Si5(2-) Journal of the American Chemical Society. Jun, 2004 | Pubmed ID: 15174843 Synthesis and Characterization of Transition-metal Zintl Phases: Cs24Nb2In12As18 and Cs13Nb2In6As10 with Isolated Complex Anions Inorganic Chemistry. Dec, 2003 | Pubmed ID: 14658914 Derivatization of Deltahedral Zintl Ions by Nucleophilic Addition: [Ph-Ge9-SbPh2]2- and [Ph2Sb-Ge9-Ge9-SbPh2]4- Journal of the American Chemical Society. Nov, 2003 | Pubmed ID: 14611242 Novel Mixed-valence Heteropolyoxometalates: a Molybdenum Diphosphonate Anion [MoV7MoVIO16(O3PPhPO3H)4]3- and Its One- and Two-dimensional Assemblies Inorganic Chemistry. Nov, 2003 | Pubmed ID: 14577801 [Ge9=Ge9=Ge9=Ge9]8-: a Linear Tetramer of Nine-atom Germanium Clusters, a Nanorod Inorganic Chemistry. Sep, 2003 | Pubmed ID: 12971742 [Mo5VMo7VIO30(BPO4)2(O3P-Ph)6]5-: a Phenyl-substituted Molybdenum(V/VI) Boro-phosphate Polyoxometalate Inorganic Chemistry. Mar, 2003 | Pubmed ID: 12611535 Synthesis and Characterization of Transition-metal Zintl Phases: K(10)NbInAs(6) and K(9)Nb(2)As(6) Inorganic Chemistry. Feb, 2003 | Pubmed ID: 12562206 Cubane with a Handle: [[In(3)As(4)Nb]-As](7-) in Cs(7)NbIn(3)As(5) Angewandte Chemie (International Ed. in English). Apr, 2002 | Pubmed ID: 12491269 Synthesis and Characterization of K(38)Nb(7)As(24) and Cs(9)Nb(2)As(6): the First Mixed-valence Transition-metal Zintl Phases Inorganic Chemistry. Nov, 2002 | Pubmed ID: 12401102 [Ge(9)=Ge(9)=Ge(9)](6-): a Linear Trimer of 27 Germanium Atoms Journal of the American Chemical Society. Sep, 2002 | Pubmed ID: 12224941 Synthesis and Characterization of [Mo(7)O(16)(O(3)PCH(2)PO(3))(3)]:(8-) a Mixed-valent Polyoxomolybdenum Diphosphonate Anion with Octahedrally and Tetrahedrally Coordinated Molybdenum Inorganic Chemistry. Jul, 2002 | Pubmed ID: 12132930 Niobium-arsenic Zintl Phases: A(6)NbAs(5) (A = K, Rb, Cs), K(6)NbTlAs(4), and K(8)NbPbAs(5) with Edge-bridged Niobium-centered Tetrahedra of Arsenic, [NbAs(4)M](n-) Where M = As, Tl, Pb Inorganic Chemistry. Jun, 2002 | Pubmed ID: 12033887 KBa(2)InAs(3) with Coexisting Monomers of [In(2)As(7)](13-) and Their One-dimensional Polymers Inorganic Chemistry. Apr, 2002 | Pubmed ID: 11952387 Naked Clusters of 56 Tin Atoms in the Solid State Journal of the American Chemical Society. Apr, 2002 | Pubmed ID: 11916421 [Ph(2)Bi-(Ge(9))-BiPh(2)](2-): a Deltahedral Zintl Ion Functionalized by Exo-bonded Ligands Journal of the American Chemical Society. Mar, 2002 | Pubmed ID: 11890785 A Reduced Polyoxomolybdenum Borophosphate Anion Related to the Wells-Dawson Clusters Journal of the American Chemical Society. Feb, 2002 | Pubmed ID: 11829590 Synthesis and Characterization of Cs(5)P[Mo(4)O(14)(OH)](2).2H(2)O: a New Molybdophosphate Cluster with Face-sharing MoO(6) Octahedra Inorganic Chemistry. Jan, 2002 | Pubmed ID: 11782155 Synthesis and Characterization of RbLi(7)Ge(8) with Isolated Closo- Angewandte Chemie (International Ed. in English). Apr, 2001 | Pubmed ID: 11317317 Arachno- Angewandte Chemie (International Ed. in English). Mar, 2001 | Pubmed ID: 11268100 Deltahedral Clusters in Neat Solids: Synthesis and Structure of the Zintl Phase Cs(4)Pb(9) with Discrete Pb(9)(4-) Clusters Inorganic Chemistry. Jul, 1998 | Pubmed ID: 11670498 Synthesis and Structure of the Zintl-Phase K(4)Pb(9) Containing Isolated Pb(9)(4)(-) Clusters of Two Different Geometries Inorganic Chemistry. Mar, 1998 | Pubmed ID: 11670346 Synthesis, Characterization, and Bonding of Heteroatomic Clusters: Na(13)Cd(20)E(7) (E = Pb, Sn), a Further Example of a Structure Containing Empty Icosahedra Without an Element of Group 13 Inorganic Chemistry. Sep, 1997 | Pubmed ID: 11670084 Co(5)BP(3)O(14): The First Borophosphate with Planar BO(3) Groups Connected to PO(4) Tetrahedra Inorganic Chemistry. Nov, 1996 | Pubmed ID: 11666863 Syntes av nio atom Deltahedral Zintl Joner av germanium och deras funktionalisering med organiska grupper Miriam M. Gillett-Kunnath1, Slavi C. Sevov1 1Department of Chemistry and Biochemistry, University of Notre Dame JoVE 3532 Biologia
Syntes av nio atom Deltahedral Zintl Joner av germanium och deras funktionalisering med organiska grupper Miriam M. Gillett-Kunnath1, Slavi C. Sevov1 1Department of Chemistry and Biochemistry, University of Notre Dame JoVE 3532 Biologia