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功能化的合成与表征金属 - 有机骨架

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Chemistry

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JoVE Journal Chemistry

Synthesis and Characterization of Functionalized Metal-organic Frameworks

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功能化的合成与表征金属 - 有机骨架

DOI:

10.3791/52094-v

•

11:27 min

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September 05, 2014

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Olga Karagiaridi, Wojciech Bury², Amy A. Sarjeant, Joseph T. Hupp, Omar K. Farha³

¹Department of Chemistry,Northwestern University, ²Department of Chemistry,Warsaw University of Technology, ³Department of Chemistry, Faculty of Science,King Abdulaziz University

Chapters

00:05Title
02:39Synthesis of the Parent Metal-organic Framework, Br-YOMOF
04:11Characterization by Power X-ray Diffraction
05:20Performing Solvent-assisted Linker Exchange on Br-YOMOF Crystals
06:59Activating SALEM-5 Crystals with Supercritical CO₂ Drying
08:53Results: Synthesis and Characterization of Intentionally Designed Metal-organic Frameworks
10:33Conclusion

Summary

Automatic Translation

合成的有意设计的金属 - 有机骨架材料，激活和表征是具有挑战性的，尤其是当构建块是不相容的或不需要的多晶型物都在期望的形式热力学上有利的。我们描述了如何通过超临界CO ₂的干燥溶剂辅助的接头交换，粉末X射线衍射中的毛细血管和激活的应用程序，可以解决这些挑战。

Tags

Metal-organic Frameworks MOFs Porosity Solvothermal Synthesis Solvent-assisted Linker Exchange Powder X-ray Diffraction Supercritical CO2 Drying Brunauer-Emmett-Teller Analysis Nitrogen Isotherms Surface Area

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