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使用气性金属-有机框架（MoF）开发异构异构选择性催化剂

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Chemistry

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JoVE Journal Chemistry

Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks (MOFs)

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使用气性金属-有机框架（MoF）开发异构异构选择性催化剂

DOI:

10.3791/60624-v

•

08:25 min

•

January 17, 2020

•

Jeehwan Han*¹, Seongwoo Kim*², Mi Sun Lee, Min Kim, Nakcheol Jeong

¹Department of Chemistry,Korea University, ²Department of Chemistry and BK21Plus Research Team,Chungbuk National University

Chapters

00:04Title
00:58(S)-KUMOF-1 Crystal Preparation
03:06Zinc/(S)-KUMOF-1 Crystal Preparation
03:55Titanium/(S)-KUMOF-1 Crystal Preparation
04:44Carbonyl-ene Reaction
06:01Results: Representative Heterogeneous Enantioselective Catalysis
07:36Conclusion

Summary

Automatic Translation

在这里，我们提出了一个协议，通过比较化学计量和催化碳基-ene反应，以找出反应是否发生在金属-有机框架的内表面或外表面，金属-有机框架的活性现场验证。

Tags

Heterogeneous Enantioselective Catalysts Chiral Metal-organic Frameworks (MOFs)Reaction Site Validation MOF-based Catalyst Characterization KUMOF-1 Synthesis Copper(II)nitrate Dicarboxylic Acid Ligand Microwave Reactor DEF DCM DMA Zinc/KUMOF-1 Crystal Preparation Dimethyl Zinc

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