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使用气性金属-有机框架 (MoF) 开发异构异构选择性催化剂
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JoVE Journal
Chemistry
Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks (MOFs)
Please note that all translations are automatically generated.
Click here for the English version.
使用气性金属-有机框架 (MoF) 开发异构异构选择性催化剂
DOI:
10.3791/60624-v
•
08:25 min
•
January 17, 2020
•
Jeehwan Han*
1
,
Seongwoo Kim*
2
,
Mi Sun Lee
,
Min Kim
,
Nakcheol Jeong
1
Department of Chemistry
,
Korea University
,
2
Department of Chemistry and BK21Plus Research Team
,
Chungbuk National University
Chapters
00:04
Title
00:58
(
S
)-KUMOF-1 Crystal Preparation
03:06
Zinc/(
S
)-KUMOF-1 Crystal Preparation
03:55
Titanium/(
S
)-KUMOF-1 Crystal Preparation
04:44
Carbonyl-ene Reaction
06:01
Results: Representative Heterogeneous Enantioselective Catalysis
07:36
Conclusion
Summary
Automatic Translation
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Automatic Translation
在这里,我们提出了一个协议,通过比较化学计量和催化碳基-ene反应,以找出反应是否发生在金属-有机框架的内表面或外表面,金属-有机框架的活性现场验证。
Tags
Heterogeneous Enantioselective Catalysts
Chiral Metal-organic Frameworks (MOFs)
Reaction Site Validation
MOF-based Catalyst Characterization
KUMOF-1 Synthesis
Copper(II)nitrate
Dicarboxylic Acid Ligand
Microwave Reactor
DEF
DCM
DMA
Zinc/KUMOF-1 Crystal Preparation
Dimethyl Zinc
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